https://store.codesys.com/en/codesys-v35-basic-programming-manual.html (Free, but requires registration)
For the user manual, there isn't a single "master" PDF, as the official documentation is primarily managed through the CODESYS Online Help . However, you can download specific modular guides and training manuals provided by manufacturers and the developer. Official Documentation & Guides codesys 35 user manual pdf
Download it and keep it locally. If you are new to IEC 61131-3, do not start with this PDF. Start with the "CODESYS Tutorial" or YouTube videos, and use this manual only when you need the definitive technical explanation of a function block. https://store
Low-level assembly-like language (deprecated in newer versions). there isn't a single "master" PDF